The MPI-Mainz UV/VIS Spectral Atlas

of Gaseous Molecules of Atmospheric Interest

www.uv-vis-spectral-atlas-mainz.org

Hannelore Keller-Rudek1, Geert K. Moortgat2, Rolf Sander2, Rüdiger Sörensen1

1Satellite Group

2Atmospheric Chemistry Division

Max-Planck Institute for Chemistry
Mainz, Germany


Home

Cross Sections

Quantum Yields

Errata

Contact, Imprint, Acknowledgements


When referring to the Spectral Atlas, please cite our publication:

Keller-Rudek, H., Moortgat, G. K., Sander, R., and Sörensen, R.: The MPI-Mainz UV/VIS spectral atlas of gaseous molecules of atmospheric interest, Earth Syst. Sci. Data, 5, 365–373, (2013), DOI: 10.5194/essd-5-365-2013


Cross Sections / Organics (carbonyls) / Ketones,ketenes / CH3C(O)CH3 / Gierczak(1998)_235K_215-349nm(calc)

DATAFILE: CH3C(O)CH3_Gierczak(1998)_235K_215-349nm(calc).txt
NAME: dimethyl ketone, acetone, propanone
FORMULA: CH3C(O)CH3
AUTHOR(YEAR): Gierczak(1998)
T: 235K
λ: 215-349nm(calc)
BIBLIOGRAPHY: T. Gierczak, J.B. Burkholder, S. Bauerle, and A.R. Ravishankara, "Photochemisty of acetone under atmospheric conditions", Chem. Phys. 231, 229-244 (1998); DOI: 10.1016/S0301-0104(98)00006-8
COMMENTS: Absorption measurements over the temperature range of 235 to 298 K using a diode array spectrometer with a resolution of 0.5 nm.

The listed data have been calculated using the data measured at 298 K, the parameterization for the temperature dependence (eqn.10)

σ(λ,T) = σ(λ,298K) × [1 + c1(λ)T + c2(λ)T2]

and the coefficients c1(λ) = ∑a1λi and c2(λ) = ∑biλi with

-----------------------------------------------------------------
i    ai        bi
------------------------------------------------------------------
0   13.1852       -4.45238×10-2
1   -2.52309×10-1    8.51385×10-4
2    1.92398×10-3   -6.48766×10-6
3   -7.30847×10-6    2.46273×10-8
4    1.3832×10-8     -4.65788×10-11
5   -1.04375×10-11   3.51253×10-14

valid over the range 215 to 330 nm
(for λ > 300 nm the c1 and c2 coefficients are those calculated at 330 nm)

Search cross sections

Species search:

Identifier search:

Reference search:

Full text search:

Recent additions:
since ago